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    • Research Publications
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    • NEWS
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  • Home
  • Research Publications
  • Research Interests
  • Research Group Members
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Chemical Record Guest Editorship

A special issue on Nucleoside/Nucleotide or Nucleic Acid Modification has been compiled as a part of the Guest Editorship invitation from Wiley for the journals, The Chemical Record and Asian Journal of Organic Chemistry. Feel free to contact me or other editors for a contribution. 

Research at ICT

Rational Ligand Design for Efficient and Sustainable Palladium Cataltysis for Nucleoside Modification

Our developed water-soluble ligand KapdiPhos ( 4-((1R,3R,5S,7R)-1,3,5-Triaza-7-phosphaadamantan-1-ium-1-yl)butane-1-sulfonate or PTABS) in combination with Pd precursor has proved to be highly efficient in catalyzing room temperature amination, low temperature etherification and thioetherification of chloroheteroarenes. Low temperature and pressure carboamidation of DMT protected nucleosides also can be achieved. 

KapdiPhos (PATBS) is now available commercially from Strem Chemicals Inc.  https://www.strem.com/catalog/v/15-5715/phosphorus_1430837-91-4 

Novel Methodologies for Heteroarenes Functionalization

C-C Bond forming technologies for heteroarene modification via transition-metal catalyzed processes such as cross-coupling & C-H bond functionalizations have dominated the literature for the past several decades. Our group has been working towards the development of newer technologies that could provide a more efficient, ambient temperature protocols for the functionalization of commercially and biologically relevant heteroaryl substrates. Our results with Palladium as well as Copper in combination with PTABS (KapdiPhos) suggests a  new coordination/activation metal-mediated SNAr of chloroheteroarenes. 

Welcome to Prof. Mahesh Lakshman (CCNY)

U.S. FULBRIGHT-NEHRU SENIOR SCHOLAR RESEARCH GRANT (FLEX) Awardee

Prof. Lakshman will be with us for 3 months in 2022 and 2-3 months in 2023. Collaboratively, we will be developing efficient routes towards important nucleoside-based antivirals. 

British Council STUDY UK Alumni Award Finalist 2021-22

https://www.britishcouncil.in/study-uk/alumni-awards/meet-the-winners

INDIA-UK Innovation & sustainability chemistry consortium

Website: https://indouk-iscc.net/

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