Research Publications

2023

Sahu, R., Yadav, S., Nath, S., Banerjee, J., Kapdi A. R. DNA-Encoded Libraries Via Late-Stage Functionalization Strategies: Chem. Commun. 2023, 59, 6128-6147 (Invited article for a special issue on Pioneering Investigators 2023)
Shet, H., Gunturu, C., Durga S. K., Gupta, K., Gharpure, S. J., Dandela, R., Kapdi, A. R. Cu(II)/PTABS-promoted, DFT-predicted regioselective SNAramination of polychlorinated pyrimidines with mechanistic understanding. J. Org. Chem. 2023, 88, 11036-11044.
Siva Sankar Murthy Bandaru, Jagrut Shah, Shatrughn Bhilare,Carola Schulzke, Anant R. Kapdi, Julien Roger, and Jean-Cyrille Hierso Phosphine Ligands Bearing the Ferrocenyl Skeleton: Advances in Catalytic Cross-Couplings. Coord. Chem. Rev. 2023, 491, 215250.
Patel, M., Kapdi, A. R. Ambient Temperature, Metal-Free, CDI-Mediated Ex-Situ Conversion of Acids to Amides: Useful Late-Stage Strategy. Chem. Asian J. 2023
Sahu, R., Yadav, S., Gunturu, K. C., Kapdi, A. R. Phenothiazine-based Cu(II)-Selective Fluorescent Sensor: GHK-Cu sensing applications. J. Org. Chem. 2023.
Gaware, S., Chatterjee, R., Kapdi, A. R., Dandela, R. Zinc-catalyzed transamidation and esterification of N-benzoyl cytosine via C–N bond cleavage. Org. Biomol. Chem. 2023, 21, 5176-5180.
Gaware, S., Chatterjee, R., Kapdi, A. R., Dandela, R. Copper-catalysed chemoslective C–OH bond activation of N-benzoyl cytosine: A facile access to 2-(dimethylamino)pyrimidine. Org. Biomol. Chem. 2023, 21, 5944-5948.
Shet, H., Sahu, R., Sanghvi, Y. S., Kapdi, A. R. Palladium-Catalyzed Cyanation of Nucleosides: Total Synthesis of Toyocamycin, Tubercidin & Sangivamycin. Synlett 2023, (invited article for special issue on nucleosides, nucleotides and oligonucleotides-Centenary year celebration of Prof. Har Gobind Khorana)
Kapdi, A. R., Sahu, R. PTABS: A Unique Water-Soluble π-Acceptor Caged Phosphine. Synlett, 2023, 34, 912-930.
Khandagale, D., Kori, S., Kapdi, A. R. DMSO-Assisted K3PO4-Catalyzed Cooperative Metal-Free Etherification of Chloroheteroarenes at Low Temperature. Chem. Asian J. 2023.
Shet, H., Patel, M., Sanghvi, Y. S., Waikar, J. M., More, P. M., Kapdi, A. R. Room Temperature Dialkylamination of ChloroHeteroarenes Using Cu(II)/PTABS Catalytic System. Chem. Asian J. 2023, 18, e202201006
Gaware, S., Kori, S., Serrano, J. L., Dandela, R., Hilton, S., Sanghvi, Y. S., Kapdi, A. R. Rapid Continuous Flow Synthesis of Nucleoside Analogues via Suzuki-Miyaura Coupling and Heck Alkenylation of 5-Iodo-2'-deoxyuridine (or cytidine). J. Flow. Chem. 2023
Editorial for special issue on Nucleoside/Nucleotide or Nucleic Acid modification. Kapdi, A. R., Arseniyadis, S., Lakshman, M. Chem. Rec. 2023, 23, e202200252

2022

Shet, H., Kapdi, A. R. Late stage C-H functionalization: Synthesis of natural products and pharmaceuticals. In Transition-Metal-Catalyzed C-H Functionalization of Heterocycles. Eds. Punniyamurthy, T., Kumar A. Wiley, New Jersey
Kori, S., Khandagale, D., Sanghvi, Y. S., Serrano, J. L., Lozano, P., Kapdi, A. R. Suzuki-Miyaura, Heck, and amidation of DMT-protected 5-iodo-2’-deoxyuridine via palladium-catalyzed reactions. Curr. Protoc. Nucleic Acid Chemistry2022.
Shet, H.; Sahu, R.; Sanghvi, Y. S.; Kapdi, A. R. Strategies for the Synthesis of Fluorinated Nucleosides, Nucleotides and Oligonucleotides. Chem. Rec. 2022, 22, e202200066 .
Kapdi, Anant; Sable, Dhanashri; Gholap, Aniket; Prasad Kommyreddy, SaiDurga; Fartade, Dipak; Gharpure, Santosh; Schulzke, Carola. Heteroatom-Assisted Regio- and Stereoselective Palladium-Catalyzed Carboxylation of 9-Allyl Adenine. J. Org. Chem. 2022, 87, 12574-12585.
Kori, S., Bhujbal, Y., Vadagaonkar, K. S., Kapdi, A. R., Prasad Kommireddy, S., Gharpure, S. Room temperature palladium-catalyzed C-H bond functionalization of benzothiazoles with iodo(hetero)arenes. Chem. Commun. 2022, 58, 847-850.
Serrano, J. L., Pérez, A., Pérez, J., Lozano, P., Gaware, S., Kori, S., Dandela, R., Sanghvi, Y. S., Kapdi, A. R. Quadrol- Pd(II) complexes: phosphine-free precatalysts for the room-temperature Suzuki-Miyaura synthesis of nucleoside analogues in aqueous media. Dalton Trans. 2022, 51, 2370-2384.

2021

Chaubey, N. R.; Kapdi, A. R. HFIP promoted one-pot thio-heteroarylation of imidazopyridines under metal- and base-free conditions. Chem. Commun. 2021, 57, 8202-8205.
Parmar, U., Kapdi, A. R. 3,5-Diaza-1-azonia-7-phosphatricyclo[3.3.1.13,7]decane, 1-(4-sulfobutyl)-, inner salt Encyclopedia of Reagents in Organic Synthesis (EROS) 2021 (first update).
Parmar, U., Somvanshi, D., Kori, S., Desai, A., Dandela, R., Maity, D. K., Kapdi, A. R. Cu(II)/PTABS: Versatile Water-Soluble Recyclable Catalyst System for Pd-Free Room Temperature Amination of Chloroheteroarenes in Water. J. Org. Chem. 2021, 86, 8900-8925.
Rajput, S., Muley, S., Kulkarni, K. S., Kapdi, A. R., Patwardhan, A. V. Synthesis of versatile diglycolamide grafted dendritic polymer and using it as a ligand for metal partitioning. J. Ind. Chem. Soc. 2021, 98, 100084.
Sable, D., Kapdi, Vadagaonkar, K., Kapdi, A. R., Bhanage, B. M. Carbon dioxide based methodologies for the synthesis of fine chemicals. Org. Biomol. Chem. 2021, 19, 5725-5757.
Shet, H., Parmar, U., Bhilare, S., Kapdi, A. R. A comprehensive review of the caged phosphines: Synthesis catalysis and future perspective. Org. Chem. Front. 2021, 8, 1599-1656.
Bhilare, S., Murthy Bandaru, S., Schulzke, C., Kapdi, A. R. 1,3,5-Triaza-7-phosphaadamantane (PTA) derived caged phosphines for palladium-catalyzed selective functionalization of nucleosides and heteroarenes. Chem. Rec. 2021, 21, 188-203.
Chaubey, N., Kapdi, A. R., Maity, B. Organophotoredox-Catalyzed C–H Alkylation of Imidazoheterocycles with Malonates: Total Synthesis of Zolpidem. Synthesis 2021, 53, 1524-1530

2020

Serrano, J. L., Garcia, L., Perez, J., Lozano, P., Correia, J., Sanghvi, Y. S., Kapdi, A. R. Water-soluble imine-palladacycles as phosphine-free efficient precatalysts for low temperature Suzuki-Miyaura synthesis of nucleoside analogues. Organometallics 2020, 39, 4479-4490.
Patil, M., Shah, J., Vijay Kumar, A., Kapdi, A. R. Photo-induced sp3 C–H bond arylation, cyanation and nitroalkylation of tetrahydroisoquinolines (THIQs) under visible light irradiation using a combination of NHPI and Rose Bengal. Chem. Asian J. 2020, 15, 4302-4306.
Shet, H., Bhilare, S., Sanghvi, Y. S., Kapdi, A. R. Tandem homometallic and multimetallic catalysis for nucleoside modification. Curr. Protoc. Nucleic Acid Chem. 2020, 83, e117.
Bhilare, S., Kori, S., Shet, H., Balaram, G., Mahendar, K., Sanghvi, Y. S., Kapdi, A. R. Scale-up of a Heck alkenylation reaction: Application to the Synthesis of an Amino-modified nucleoside “Ruth Linker” Synthesis PSP 2020, 52, 3595-3603
Ardhapure, A. A., Gayakhe, V., Bhilare, S., Kapdi, A. R., Sanghvi, Y. S., Bag, S. S., Gunturu, C. Extended fluorescent uridine analogues: Synthesis, photo-physical properties and selective interaction with BSA protein. New J. Chem. 2020, 14744-14754.
Shet, H., Bhilare, S., Sanghvi, Y. S., Kapdi, A. R. Discovery, Synthesis, and Scale-up of Efficient Palladium Catalysts Useful for the Modification of Nucleosides and Heteroarenes Molecules 2020, 25, 1645 (Invited article for a special issue on Transition Metal-Catalyzed Reactions in Heterocyclic Synthesis)
Gholap, A., Bag, S., Pradhan, S., Kapdi, A. R., Maiti, D. Diverse meta-C-H functionalization of free amides. ACS Catal., 2020, 10, 5347-5352.
Bhilare, S., Shah, J., Kapdi, A. R. 3,5-Diaza-1-azonia-7-phosphatricyclo[3.3.1.13,7]decane, 1-(4-sulfobutyl)-, inner salt Encyclopedia of Reagents in Organic Synthesis (EROS) 2020.
Bandaru, S. M., Shah, J. A., Bhilare, S., Schulzke, C., Kapdi. A. R., Hierso, J.C. Phosphine Ligands bearing ferrocenyl skeleton: Advances in catalytic cross-couplings. Wiley Book chapter 2020.
Girase, T., Bhilare, S., Bandaru S. S. M., Chryosochos, N., Schulzke, C., Sanghvi, Y. S., Kapdi, A. R. Carbazole-Based N-Heterocyclic Carbenes for the Promotion of Copper-Catalyzed Palladium-Free Homo-/Hetero-Coupling of Alkynes and Sonogashira Reactions. Asian J. Org. Chem. 2020, 9, 274-291 .
Girase, T., Patil, K. S., Kapdi, A. R., Gupta, G. R. Palladium acetate/[CPy][Br]: an efficient catalytic system towards the synthesis of biologically relevant stilbene derivatives via Heck cross-coupling reaction. Chem. Select, 2020, 5, 4251-4262.
Gupta, G., Girase, T., Kapdi, A. R. Diels-Alder reactions in Ionic Liquids: Encyclopedia of ionic Liquids. Ed. Bhanage, B. M. Springer, 2020.

2019

Bhujbal, Y., Vadagoankar, K., Sanghvi, Y. S., Gholap, A., Dandela, R., Kapdi, A. R. HFIP Promoted Low-Temperature SNAr of ChloroHeteroarenes Using Thiols and Amines. J. Org. Chem. 2019, 84, 15343-15354.
Bhilare, S., Shah, J., Gaikwad, V., Gupta, G., Sanghvi, Y. S., Bhanage, B. M., Kapdi, A. R. Pd/PTABS: An efficient catalytic system for the aminocarbonylation of nucleosides. Synthesis 2019, 51, 4239-4248
Murthy Bandaru, S. S., Bhilare, S., Cardozo, J., Chrysochos, N., Schulzke, C., Sanghvi, Y. S., Gunturu, K. C., Kapdi, A. R. Pd/PTABS: Low temperature thioetherification of chloroheteroarenes. J. Org. Chem. 2019, 84, 8921-8940.
Gupta, G., Shah, J., Vadagaonkar, K. S., Lavekar, A. G., Kapdi, A. R. Hetero-bimetallic Cooperative Catalysis for the Synthesis of Heteroarenes. Org. Biomol. Chem. 2019, 17, 7596-7631. (As a part of a special issue on New Talent in the World)
Sable, V., Sharma, A., Shah, J., Kapdi, A. R. Pd Colloids-Catalyzed General and Selective Oxidative Esterification of Benzylic alcohols. Chem Asian J. 2019, 2639-2647.
Girase, T., Kapdi, A. R. Novel Carbazole-based N-Heterocyclic Carbene Ligands for Accessing Synthetically Relevant Stilbenes via Pd-Catalyzed Coupling Processes. Chem. Asian J. 2019, 2611-2619.
Zende, V., Girase, T. R., Chryosochos, N., Schulzke, N. Amido-functionalized N-heterocyclic carbene ligands and corresponding palladium complexes: Synthesis, characterization and catalytic activity. J. Organomet. Chem. 2019, 888, 44-53.
Bhujbal, Y.B., Vadagaonkar, K. S., Kapdi, A. R. Pd/PTABS: Catalyst for Efficient C-H (Hetero)arylation of 1,3,4-Oxadiazoles Using Bromo(Hetero)arenes, Asian J. Org. Chem., 2019, 8, 289-295. (Cover page)
Gupta, G., Girase, T., Kapdi, A. R. Diels-Alder reactions in Ionic Liquids: Encyclopedia of ionic Liquids. Springer, 2019.
Kapdi, A. R.,* Rajput, S., Patwardhan, A. V. Dendritic Polymers and Multifunctional Supports. "Applications of One Dimensional Nanomaterials"Ed. Chaughule, R. S. American Scientific Publishers, USA.2019.
Gupta, G., Bhilare, S., Maiti, D., Kapdi, A. R. Miscellaneous applications of Palladacycles. Palladacycles: Catalysis and Beyond. Volume 3: Latest Trends in Palladium Chemistry) Eds. A. R. Kapdi, D. Maiti. Elsevier, New York, 2019 pgs 371-395 .
Bangde, P., Prajapati, D., Dandekar-Jain, P., Fairlamb, I. J. S., Kapdi, A. R. Palladacycles as potential anticancer agents. Palladacycles: Catalysis and Beyond. Volume 3: Latest Trends in Palladium Chemistry) Eds. A. R. Kapdi, D. Maiti. Elsevier, New York, 2019 pgs 343-370

2018

Wang, W., Lorion, M., Shah, J., Kapdi, A. R., Ackermann, L. Late stage peptide diversification by position-selective C-H activation. Angew. Chem. Int. Ed. 2018, 57, 14700-14717.
Murthy Bandaru, S., Bhilare, S., Chryosochos, N., Gayakhe, V., Trentin. I., Schulzke, C., Kapdi, A. R.*, Pd/PTABS: Catalyst for Room Temperature Amination of Heteroarenes. Org. Lett. 2018, 20, 473-476.
Bhilare, S., MuthryBandaru, S., Shah, J., Chrysochos, N., Schulzke, C., Sanghvi, Y. S., Kapdi, A. R. Pd/PTABS: Low Temperature Etherification of Chloroheteroarenes. J. Org. Chem. 2018, 83, 13088-13102.
Sable, V., Maindan, K., Bhilare, S., Kapdi, A. R., Chrysochos, N., Schulzke, C. An Active Palladium Colloidal Catalyst For the Selective Oxidative Heterocoupling of (Hetero)Aryl Boronic Acids. Chem. Asian J. 2018 as an invited article for the themed issue ‘Homogeneous Catalysis from Asia: Emerging scientists’.
Shelke, Y. G., Yashmeen, A., Gholap, A., Gharpure, S. J., Kapdi, A. R. Homogeneous catalysis: Powerful technology for the modification of Bio-Active molecules. Chem. Asian J. 2018, 13, 2991-3013.
Wong, S. M., Choy, P. Y., Kapdi, A. R.,* Kwong, F. Y.,* Recent Developments of Palladium-Catalysed Non-Directed Coupling of (Hetero)arenes C-H Bond with C-Z (Z = B, Si, Sn, S, N, and H) bonds. Org. Chem. Front. 2018, 5, 288-321.
Bangde, P., Prajapati, D., Dandekar-Jain, P., Kapdi, A. R. New Water soluble N-Heterocyclic carbene palladium complexes as promising anti-tumouragents: investigating DNA and protein interactions. Chem. Select, 2018, 3, 5709-5716.
Ardhapure, A. Kapdi, A. R., Borozdina, Y., Sanghvi, Y. S., Schulzke, C. Crystal Structure of 8-(4-Methylphenyl)-2'-deoxyadenosine. Acta Crystallographica E. 2018, E74, 1-5.
Bandaru, S. M., Kapdi, A. R. and Schuzlke, C. Crystal structure of 4-(Pyrazin-2-yl)morpholine. Acta Crystallographica E. 2018, E74, 137-140.
Gayakhe, V., Bhilare, S., Yashmeen, A., Kapdi, A. R.,* Fairlamb, I. J. S. In Transition Metal-Catalysed Modifications of Nucleosides: Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides. Volume 2: Latest Trends in Palladium Chemistry) Eds. A. R. Kapdi, D. Maiti, Y. S. Sanghvi. Elsevier, New York, 2018 pgs 167-195.
Ardhapure, A. V., Gholap, A., Kapdi, A. R.,* Schulzke, C. In Stille Cross-Coupling Reaction: Early years to the current state-of the art..: Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides. Volume 2: Latest Trends in Palladium Chemistry) Eds. A. R. Kapdi, D. Maiti, Y. S. Sanghvi. Elsevier, New York, 2018 Pgs 19-36.
Sanghvi, Y. S., Kapdi, A. R. In Future of Drug Discovery: Importance of modified nucleosides, nucleotides and oligonucleotides: Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides. Volume 2: Latest Trends in Palladium Chemistry) Eds. A. R. Kapdi, D. Maiti, Y. S. Sanghvi. Elsevier, New York, 2018 pgs 1-18.
Bhilare, S., Bandaru, S., Kapdi, A. R., Sanghvi, Y. S., Schulzke, C. Pd/PTABS: An Efficient Water Soluble Catalytic System for the Amination of 6-Chloropurine Ribonucleoside and Synthesis of Alogliptin. Curr. Protoc. Nucleic Acids Chem. 2018, 74, 58.
Zende, V., Girase, T. S., Chrysochos, N., Kapdi, A. R., Schulzke, C. Crystal structure of 1-butyl-3-(2-((2,3-dihydro-1H-indenyl-5-yl)amino)-2-oxo-ethyl)-1H-imidazol-3-ium chloride. Acta Crystallographica E. 2018, E74, 1665-1668

2017

Lorion, M. M., Maindan, K., Kapdi, A. R.,* Ackermann, L.* Heteromultimetallic Catalysis for Sustainable Organic Syntheses. Chem. Soc. Rev. 2017, 46, 7399-7420.
Sable, V., Maindan, K., Shejwalkar, P., Hara, K., Kapdi, A. R.* Active Palladium Colloids via Palladacycle Degradation as Efficient Catalysts for Oxidative Homocoupling and Cross-Coupling of Aryl Boronic Acids. ACS Omega, 2017, 2, 204-217.
Gayakhe, V., Gholap, A., Kapdi, A. R.* In Mechanistic/ Organometallic Aspects of Palladium Catalyzed C–H Bond Functionalization.: Strategies for Palladium-Catalyzed Non-Directed and Directed C-H Bond Functionalization. Volume 1: Latest Trends in Palladium Chemistry) Eds. A. R. Kapdi, D. Maiti, Elsevier, New York, 2017, pp 417-452.
Kapdi, A. R.,* Maiti, D.* Dey, A. Introduction to Non-directed and Directed C-H bond functionalisation: Strategies for Palladium-Catalyzed Non-Directed and Directed C-H Bond Functionalization. (Volume 1: Latest Trends in Palladium Chemistry) Eds. Kapdi A. R., Maiti, D. Elsevier, New York, 2017, pp 1-8.
Fairlamb, I. J. S., Kapdi, A. R.* In Directed C-H bond functionalization strategies for synthesis.: Strategies for Palladium-Catalyzed Non-Directed and Directed C-H Bond Functionalization. Volume 1: Latest Trends in Palladium Chemistry) Eds. A. R. Kapdi, D. Maiti, Elsevier, New York, 2017, pp 9-48.
Dhangar, G., Serrano, J. L., Schulzke, C., Gunturu, K. C., Kapdi, A. R.* Palladacycle-Catalyzed Triple Suzuki Coupling Strategy for the Synthesis of Anthracene Based OLED Emitters. ACS Omega, 2017, 2, 3144-3156.
Gholap, A., Maity, S., Maiti, D.,* Schulzke, C., Kapdi, A. R.* Synthesis of 2,3-disubstituted quinazolinones via intramolecular Cu-catalysed CSP3-H activation/cyclisation. Org. Biomol. Chem., 2017, 15, 7140-7146.
Gaykhe, V., Kapdi, A. R., Borozdina, Y., Schulzke, C.* Crystal Structure of 5-(Dibenzofuran-4-yl)-2'-deoxyuridine. Acta Crystallographica E. 2017. E73, 1493-1496.

2016-2004

Gayakhe, V., Ardhapure, A., Kapdi, A. R.,* Sanghvi, Y. S., Serrano, J. L., Garcia, L., Perez, J., Garcia, J., Fischer, C., Schulzke, C. Water soluble Pd-imidate complexes: Broadly applicable catalysts for the synthesis of chemically modified nucleosides via Pd-catalysed cross-coupling. J. Org. Chem. 2016, 81, 2713-2729.
Gayakhe, V., Ardhapure, A., Kapdi, A. R.,* Sanghvi, Y. S., Serrano, J. L., Schulzke, C. C-C Bond Formation: Synthesis of C5 substituted Pyrimidine and C8 Substituted Purine Nucleosides Using Water Soluble Pd-imidate Complex. Current Protocols in Nucleic Acid Chemistry. 2016, 65, 1.37.
Serrano, J. L., Pérez, J. García, L., Pérez, E., Sánchez, G., Kapdi, A. R.* A convenient route to prepare mono- and dinuclear 2-Benzoylpyridine palladacycles with imidate ligands. J. Organomet. Chem. 2016, 814, 57-62.
Bhilare, S., Gayakhe, V., Ardhapure, A., Sanghvi, Y. S., Schulzke, C., Borozdina, Y., Kapdi, A. R.* ‘Novel Water-Soluble Phosphatriazenes: Versatile Ligands for Suzuki-Miyaura, Sonogashira and Heck Reactions of Nucleosides’ RSC Adv. 2016, 6, 83820.
Kapdi, A. R.,* Ardhapure, A., Sanghvi, Y. S. Modulation of the Electronic Properties of Non-innocent (E,E)-Dibenzylideneacetone for Palladium(0)-Mediated Heck-Alkenylation of 5-Iodo-2’-deoxyuridine and Scale-up Studies. Synthesis 2015, 47, 1163-1169.
Serrano, J. L.,* Perez, J., Garcia, L., Sanchez, G., Garcia, J., Lozano, P., Zende, V., Kapdi, A. R.* N-heterocyclic-carbene complexes readily prepared from di--hydroxo-palladacycles catalyze the Suzuki arylation of 9-bromophenanthrene. Organometallics 2015, 34, 522.
Kapdi, A. R.,* Ardhapure, A., Sanghvi, Y. S., Serrano, J. L.,Sánchez, J., García, J., Lozano, P. Pd-imidate complexes as recyclable catalysts for the synthesis of C5-alkenylated pyrimidine nucleosides via Heck cross-coupling reaction. RSC Advances. 2015, 5, 24558-24563.
Kapdi, A. R.,* Gayakhe, V., Sanghvi, Y. S., Fairlamb, I. J. S. Catalytic C–H Bond Functionalisation of Purine and Pyrimidine Nucleosides: A Synthetic and Mechanistic Perspective. Chem. Commun., 2015, 51, 11944-11960. (Inside cover page article).
Prajapati, D., Schulzke, C., Kindermann, M., Kapdi, A. R.,* Selective Palladium-Catalysed Arylation of Dibromopyridine Using N-Heterocyclic Carbene Ligands. RSC Advances, 2015, 5, 53073-53085.
Zende, V., Schulzke, C., Kapdi, A. R.,*Pincer CNC bis-N-Heterocyclic Carbenes: Robust Ligands for Palladium-Catalysed Suzuki-Miyaura Arylation of BromoAnthracene and Related Substrates. Org. Chem. Front. 2015, 2, 1397-1410.
Beeby*, A., Bettington, S., Fairlamb*, I. J. S., Goeta, A. E., Kapdi A. R. and Thompson, A. L.: A new precatalyst for the Suzuki reaction- a pyridyl-bridged dinuclear palladium complex as a novel source of mono-ligated palladium(0). New. J. Chem. 2004, 28, 600-605. (Cited in Chem Inform, 2004, 35, 103)
Fairlamb*, I.J.S., Kapdi, A. R.,. Lynam, J. M., Taylor*, R. J. K. and Whitwood, A. C.: Bis (triphenyl-phosphine) palladium (П) Succinimide- a new precatalyst for Suzuki cross coupling. Tetrahedron 2004, 60, 5711-5718. (Cited in Chem Inform, 2004, 35, 94)
Chaignon, N., Fairlamb*, I.J.S.,. Kapdi, A.R., Taylor*, R.J.K. and Whitwood, A.C.: Bis (triphenyl-phosphine) palladium (II) Succinimide an easily prepared precatalyst for Suzuki-Miyaura coupling reactions. J. Mol. Cat. A: Chem. 2004, 219, 191-199. (cited 11 times)
Fairlamb*, I.J.S., Kapdi, A.R. and Lee, A.: η2-dba complexes of palladium (0): electron rich dba ligands enhance the reactivity of ‘PdLn’ catalyst species in Suzuki-Miyaura coupling. Org. Lett. 2004, 6, 4435-4438. (78 citations)
Fairlamb*, I.J.S., Kapdi, A.R., Lee, A., Sanchez, G., Lopez, G., Serrano*, J. L., Garcia, L., Perez, J. and Perez. E.: Mono- and binuclear cyclometallated palladium(II) complexes containing bridging (N, O-) and terminal (N-) imidate ligands: Air stable, thermally robust and recyclable catalysts for cross-coupling processes. Dalton Trans. 2004, 3970-3981. (cited 27 times)
Crawforth, C. M., Burling, S., Fairlamb*, I.J.S., Kapdi, A.R., Taylor*, R.J.K. and Whitwood, A. C.: Oxidative addition of N-halosuccinimides to palladium (0): The discovery of neutral palladium (II) imidate complexes which enhance Stille coupling of allylic and benzylic halides. Tetrahedron 2005, 61, 9736-9751. (Cited in Chem Inform, 2006, 37, 57)
Fairlamb*, I. J. S., Kapdi, A. R., Serrano, J. L., Taylor R. J. K. and Sanchez, G.: Air stable, phosphine-free anionic palladacyclopentadienyl catalysts: Remarkable halide and pseudohalide effects in Stille coupling. Adv. Synth. Cat. 2006, 348, 405-412. (Cited in Chem Inform, 2006, 37, 52)
Macé, Y., Kapdi, A. R., Fairlamb*, I. J. S. and Jutand*, A.: Influence of the dba substitution on the reactivity of Pd(0) complexes generated from Pd02(dba-n,n' Z)3 or Pd0(dba-n,n' Z)2 and PPh3 in oxidative addition with iodobenzene. Organometallics 2006, 25, 1795-1800. (cited 31 times)
Fairlamb*, I. J. S., Kapdi, A. R., Lee, A. F., McGlacken, G. P., Weissburger F., de Vries, A. H. M. and Schmieder-van de Vondervoort, L.: Exploiting non-innocent (E,E)-dibenzylidene acetone (dba) effects in palladium(0) mediated cross-coupling reactions: modulation of the electronic properties of dba affects catalyst activity and stability in ligand and ligand-free reaction systems. Chem. Eur. J. 2006, 12, 8750 – 8761. (Cited 40 times)
Fairlamb*, I. J. S. and Kapdi, A. R.: Synthesis of substituted dibenzylidene acetone (dba) derivatives. Synthetic pages 2004, 221.
Burns, M.J., Fairlamb*, I.J.S., Kapdi, A. R., Sehnal, P. and Taylor*, R. J. K.: A simple palladium(II) precatalyst for Suzuki-Miyaura couplings: efficient reactions of benzylic, aromatic and heteroaromatic coupling partners. Org. Lett. 2007, 9, 5397-5400. (Cited in Chem Inform, 2008, 39, 93)
Ackermann*, L., Vicente, R., Kapdi, A. R.: Review Article- Transition Metal-Catalyzed Direct Arylations of (Hetero)Arenes via C–H Bond Cleavage. Angew. Chem. Int. Ed. 2009, 48, 9792-9827; Angew. Chem. 2009, 121, 9976–10012. (Cited 209 times) (Cover Page Article; Cited in Chem Inform, 2010, 41, 243)
Ackermann*, L., Weschler, C., Kapdi, A. R., Althammer, A.: Air-Stable Diaminophosphine Sulfides as Preligands for Nickel-Catalyzed Cross-Couplings of Fluoroarenes. Synlett, 2010, 294-298. (Cited in Chem Inform, 2010, 41, 76 and Synfacts)
Ackermann*, L., Potukuchi, H., Kapdi, A. R., Schulzke, C.: Efficient Kumada Cross-Coupling of 2-Pyridyl Grignard Reagent with Aryl Bromides. Chem. Eur. J. 2010, 16, 3300-3303. (Cited in Chem Inform, 2010, 41, 158)
Ackermann*, L., Kapdi, A. R., Schulzke, C.: Air-Stable Secondary Phosphine Oxide or Chloride (Pre)Ligands for Cross-Couplings of Unactivated Alkyl Chlorides. Org. Lett. 2010, 12, 2298–2301. (Cited on Organic Chemistry Portal http://www.organic-chemistry.org/abstracts/lit2/911.shtm; Cited in Chem Inform, 2010, 41, 47))
Ackermann*, L., Kapdi, A. R., Kornhass, C.; Fenner, S., Schulzke, C.: Highly Active Air-Stable Dimeric Palladium(II)- Phosphonite Complex for Efficient Kumada-Corriu Cross-Coupling of (Hetero)Aryl and Alkenyl Tosylates. Chem. Eur. J. 2011, 17, 2965-2971. (Cited in Chem Inform, 2011, 42, 86)
Ackermann*, L.; Barfusser, S.; Kornhass, C.; Kapdi, A. R. C-H bond Arylations and Benzylations on Oxazol(in)es with a Palladium Catalyst of a Secondary Phosphine Oxide. Org. Lett. 2011, 13, 3082-3085. (Cited in Chem Inform, 2011, 42, 131)
Kapdi*, A. R.; Taylor, R. J. K.; Fairlamb*, I. J. S. Highly Regio- and Chemoselective Palladium(0)-Mediated Allylic Substitution of Difunctional Allylic Halides with Phenols. Tetrahedron Lett. 2010, 51, 6378-6380.
Sirisha, P.; Pednekar*, S.; Kapdi, A. R. Facile p-TSA Catalyzed One Pot Synthesis of Tetrahydropyrimidinones Derivatives in Water and Under Solventless Condition. Bull. Catal. Soc. India 2010, 9, 138-141.
Kapdi*, A. R. Innocent Or Non-Innocent: Towards Understanding The Role Of DBA In Palladium(0) Mediated Cross-Coupling Reactions. Review article in Bull. Catal. Soc. India 2010, 9, 12-28.
Sánchez*, G.; García, J.; Martínez, M.; Pérez, J.; García, L.; Serrano, J. L.; Kapdi, A R. Bis(imidate)palladium(II) complexes with labile ligands. Mimics of classical precursors? Dalton Trans. 2011, 40, 12676-12689. (Cover Page Article)
Sirisha, P.; Pednekar*, S.; Kapdi, A. R.; Naik, M. Facile One Pot Synthesis of Pyranobenzopyran and Their Derivatives. J. Chem. Sci. 2011, 123, 667-672. (cited in Chem Inform, 2012, 43, 123)
Santana, M. D.; García-Bueno, R.; García, G.; Sánchez, G.; García, J.; Naik, M.; Pednekar, S.; Kapdi, A. R.*; Pérez, J.; García, L.; Pérez L.; Serrano, J. L*. A new route towards cyclopalladated complexes with saccharinate ligands: luminescence properties and catalytic activity. Dalton Trans. 2012, 41, 3832-3842.
Kapdi, A. R.* In Organometallic Aspects of C-H bond activation/functionalization: Specialist Periodical Reports- Organometallic Chemistry (Eds.: I. J. S. Fairlamb) RSC, Organomet. Chem. 2012, 38, 47-73 (cited in Chem Inform, 2013, 44).
Ackermann*, L., Kapdi, A. R., Kozhuskov, S. I., Potukuchi, H. In Synthesis via C-H Bond Functionalization: In Handbook of Green Chemistry Series (Green Synthesis) (Ed.: C. J. Li) Wiley, New Weinheim, 2012, 259-305.
Kapdi, A. R.*, Fairlamb, I. J. S.* In Alkynylzinc and Other Cross-Coupling: C-C Cross-Coupling and Heck Reactions. Science of Synthesis-Houben Weyl Series (Eds.: G. Molander) Thieme, Invited Book Chapter 2012.
Serrano, J. L.,* Perez, J., Garcia, L., Sanchez, G., Garica, J., Tyagi, K., Kapdi, A. R.* New Phospha-Palladacyles: Efficient Catalysts for Formylation of Aryl Chlorides. RSC Advances 2012, 2, 12237-12244.
Kapdi, A. R., Chaughule, R. S., Nanotechnology: Bridging Aspects of Catalysis, Energy and Drug Delivery Contents and Scope: Nanoparticles for Catalysis, Energy and Drug Delivery (Eds.: R. G. Chaughule and A. R. Kapdi) American Scientific Publishers, 2014.
Kapdi, A. R.* In Metal Nanoparticles: Green Catalysis in Water- Nanoparticles for Catalysis, Energy and Drug Delivery (Eds.: R. G. Chaughule and A. R. Kapdi) American Scientific Publishers, 2014.
Kapdi, A. R.*, Organometallic Aspects of Transition-Metal Catalysed Regioselective C–H Bond Functionalisation of Arenes and Heteroarenes. Dalton Trans. 2014, 43, 3021-3034 (Invited Article).
Kapdi, A. R.,* Gayakhe, V., Sanghvi, Y. S., García, J., Lozano, P., da Silva, I., Pérez, J. and Luis Serrano, J. New water soluble Pd-Imidate complexes as highly efficient catalysts for the synthesis of C5-arylated pyrimidine nucleosides via Suzuki-Miyaura cross-coupling. RSC Advances 2014, 4, 17567-17572.
Kapdi A. R.,* Fairlamb, I. J. S. Anti-cancer palladium complexes: a focus on PdX2L2 and palladacycles. Invited article to Chem. Soc. Rev. 2014, 43, 4751-4777.
Kapdi, A. R., Dhangar, G., Serrano, J. L., Perez, J., Garcia, L., Fairlamb, I. J. S.* [Pd(C^N)(X)(PPh3)] palladacycles react with 2,4,6-trifluorophenyl boronic acid without exogenous base to give stable transmetallation products of the type [Pd(C^N)(2,4,6-F3C6H2)(PPh3)]. Chem. Commun. 2014, 50, 9859.
Kapdi, A. R.,* Prajapati, D. Regioselective Palladium-Catalysed Cross-Coupling Reactions: A Powerful Synthetic Tool. Invited review for Prof. Richard Taylor’s 65th Birthday commemoration. RSC Advances. 2014, 4, 41245.
Kapdi, A. R.,* Dhangar, G., Serrano, J. L., Haro, J. D., Lazano, P., Fairlamb, I. J. S. [Pd(Phbz)(X)(PPh3)] palladacycles promote the base-free homocoupling of arylboronic acids in air at room temperature. RSC Advances. 2014, 4, 55305-55312. Shah, P. A.; Garcia, J.; Santana, M. D.; Serrano, J. L.; Naik, M.; Pednekar, S.; Kapdi, A. R*. [Pd(PPh3)2(Saccharinate)2]- General Catalyst for Suzuki-Miyaura, Negishi cross-coupling and C-H bond functionalization of coumaryl and pyrone substrates. Tetrahedron 2013, 69, 1446-1453. (Cited in Chem Inform, 2013, 44, 136)
Kapdi, A. R.,* Fairlamb, I. J. S.* Synthesis of Macrocyclic Ketones Exploiting Palladium-Catalyzed Activation of Carboxylic Acids as an Enabling Step. New J Chem. 2013, 37, 961-964 (cited in Chem. Inform, 2013, 44).
Kapdi, A. R., Whitwood, A. C., Burns, M. J., Fairlamb, I. J. S*. Dinuclear palladium(0) complexes containing symmetrical and unsymmetrical aryl substituted E,E- dibenzylidieneacetone ligands: The importance of aryl substituents and 1,4-dien-3-one conformation. J. Am. Chem. Soc. 2013, 135, 8388-8399.
A. R. Kapdi,* C. Jain, T. Padte, U. Shevde, S. Pednekar, C. Fischer and C. Schulzke, Tween-80: A Bio-degradable and Recyclable Phase Transfer Catalyst for Microwave Assisted Synthesis of Highly Substituted Dicoumarols. Int. J. Green Chem. Bioprocess 2013, 3, 17-23.
A. R. Kapdi,* A. Karbelkar, M. Naik, S. Pednekar, C. Fischer, C. Schulzkec and M. Tromp: Efficient Synthesis of coumarin based Tetra and Pentacyclic rings using Phospha-Palladacycles. RSC Advances 2013, 3, 20905-20912.